- The molecular orbitals after hybridization now form different bonds between the electrons. One carbon atom overlaps the sp 2 orbital of another carbon atom to form sp 2 – sp 2 sigma bond. The two sp 2 hybrid orbitals get overlapped by two hydrogen atoms containing unpaired electrons. A pi bond is formed by the unhybridized 2pz orbitals of ...
- Topic 7.2 (d) In ethene the double bond between the carbon atoms is made up a sigma bond and a pi bond and can be represented as unused p-orbital which can overlap with the p-orbital from the other carbon -orbital the Greek for “p” is “ " and so it is called a pi-bond. H H C C H H The pi bond is made by the overlap of two p orbitals.
- Generally sigma bonds are stronger than pi bonds. Both are used extensively to predict the behavior of molecules in molecular orbital theory. One difference between single and multiple bonds is that single bonds only have a sigma bond, whereas multiple bonds have both sigma and pi bonds.
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